量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

胜利油气区有机包裹体研究及其在油气勘探中的应用     

李荣西  金奎励  廖永胜 《地球科学与环境学报》1997,(4)

应用显微光度术、显微傅立叶红外光谱（Ｍｉｃｒｏ－ＦＴ．ＩＲ）和飞行时间二次离子质谱（ＴＯＦ－ＳＩＭＳ）等原位微分析技术并结合均一温度测量对胜利油气区下第三系沙河街组沙三段中有机包裹体进行了研究。区分出两类有机包裹体，即原生有机包裹体和次生有机包裹体。结果表明两类有机包裹体特征不同，二者物质组成、有机质成分及化学结构、热演化程度等差别也较大。结合地质分析表明原生有机包裹体是沙三段烃源岩生成烃类运移产物，具“自生自储”特点，而次生有机包裹体是沙四段烃源岩生成的烃类二次运移的产物。沙三段是沙河街组油气运移和聚集的主要层位，因而是寻找油气资源的主要目标层。研究表明，有机包裹体是研究油气生成、运移、聚集和演化等成藏系统最有效的手段之一，在油气勘探中有重要的应用意义。  相似文献   

The β Cephei instability strip     

L. Deng  D.R. Xiong 《Monthly notices of the Royal Astronomical Society》2001,327(3):881-887

We carried out a series of linear stability analyses of the radial and low-degree non-radial p modes for stellar models with initial masses of     . The stellar models were computed by using convective overshoot distance     , 0.25 and 0.40  H _P. Our numerical results show that the β Cephei instability strip forms a horn-shaped region pointing upwards near the main sequence on the Hertzsprung–Russell diagram (HRD). The lower part of the instability strip for the radial modes join the zero-age main-sequence (ZAMS) at     , while the top of the instability strip extends up to     . The instability strip for the non-radial modes is even wider. The overall instability strip is dominated by the radial and non-radial fundamental modes. The first overtone (the radial-order index     is also pulsationally unstable. We have shown that the β Cephei stability is almost independent of the overshoot parameter d _over used for the stellar models, while it depends critically on the metal abundance. With decreasing metal abundance, the instability region shrinks and eventually disappears for     .  相似文献   

卫星激光测距的新进展   总被引：6，自引：0，他引：6  

张忠萍  杨福民 《天文学进展》2001,19(2):283-288

扼要综述了近几年国际上卫星激光测距的进展，介绍了国内激光测距网的现状，展望了未来卫星激光测距的发展。  相似文献   

PROPAGATION OF 30—60 DAY LOW FREQUENCY OSCILLATIONS AND THEIR INFLUENCE UPON THE SUBTROPICAL WESTERLIES JET STREAM DURING NORTHERN HEMISPHERE WINTER          下载免费PDF全文

史玉光  李清泉 《Acta Meteorologica Sinica》1996,(2)

Based on daily ECMWF gridpoint data of two winters during 1981—1983 including an ENSOyear,propagation of low frequency oscillations(LFO)during Northern Hemisphere winters andtheir influences upon 30—60 day oscillations of the subtropical jet stream are studied with the sta-tistical methods as complex empirical orthogonal function(CEOF)and so on.Results show that inthe winter of a normal year(1981—1982),30—60 day oscillations in the subtropical zone aremainly in the northern and southern flanks of exit region of jet stream.In the ENSO year(1982—1983),they are mainly in the vicinity of entrance and exit regions of jet stream.Intraseasonalchanges of subtropical jet stream manifested themselves as latitudinal fluctuation or longitudinalprogression or regression of about 40 day period.There are marked differences between propagat-ing passages of low frequency modes responsible for changes of subtropical jet stream in the normalyear(1981—1982)and in the ENSO year(1982—1983).Changes of oscillation amplitude showobvious phases.In general,the one in late winter is stronger than that in early winter,strongestone occurs in February.  相似文献   

APPLICATION OF MAP AND FILE INFORMATIONVISUALIZATION SYSTEM TO COMPREHENSIVEDIVISION OF NATURAL DISASTERS- Takingthe ChangjiangValleg as an Example     

HU Bao-qing    JIANG Mei-xin  JUN Su-lan  ZENG Qiao-song 《中国地理科学(英文版)》2001,(4)

In recent years，scholars at home and abroad have method，and that vanous disasters would be analyzed assynthetically studied natural dlsaste‘theoretically and an Integral．SHI Peilun（1991）putforwad a scientificmethodologlcally，as well as its cases analys。s（CND，term—regional disaster system，which Indicates that1987； MA et al，1990； MARBLE，1990； NE et al，the situation of a disaster（calamity loss）results from1999； PATAK et al，1982； SHI，1991；VAN et al，h…  相似文献   

FARMLAND AND URBAN AREA DYNAMICS MONITORING INCHINA USING REMOTE SENSING AND SPATIALSTATISTICS METHODOLOGY     

LIU Ming-liang  ZHUANG Da-fang  LIU Ji-yuan 《中国地理科学(英文版)》2001,11(1):42-49

1 INTRODUCTIONGlobal change research involves much geo-objectsand geo-process, such as climate and environmentalchange, substance and energy cycling, land-use/land-cover change (LUCC), interactivity between human and nature, etc.. So it need cooperation frommany research communities including international research programs groups such as IGBP (InternationalGeosphere-Biosphere Programme IPCC (Intergovemmental Panel on Climate Change), IHDP (InternationalHuman Dimension Program o…  相似文献   

Neutron background in large-scale xenon detectors for dark matter searches     

M. J. Carson  J. C. Davies  E. Daw  R. J. Hollingworth  V. A. Kudryavtsev  T. B. Lawson  P. K. Lightfoot  J. E. McMillan  B. Morgan  S. M. Paling  M. Robinson  N. J. C. Spooner  D. R. Tovey 《Astroparticle Physics》2004,21(6):667-687

Simulations of the neutron background for future large-scale particle dark matter detectors are presented. Neutrons were generated in rock and detector elements via spontaneous fission and (α,n) reactions, and by cosmic-ray muons. The simulation techniques and results are discussed in the context of the expected sensitivity of a generic liquid xenon dark matter detector. Methods of neutron background suppression are investigated. A sensitivity of 10⁻⁹–10⁻¹⁰ pb to WIMP-nucleon interactions can be achieved by a tonne-scale detector.  相似文献   

Statistical analysis of surface hydrography and circulation variations in northern South China Sea     

吴玲娟  崔茂常 《中国海洋湖沼学报》2005,23(4):383-392

1 INTRODUCTIONThe South China Sea (SCS) is a semi-enclosedmarginal sea in western North Pacific Ocean withvery complex topography and is the important pas-sage connecting the Pacific and Indian Oceans. Ithas great impact to the global climate and a greatinterest of many oceanography researchers. Twodominant surface hydrographic and circulation fea-tures in the northern SCS are a strong fresh waterexpansion and a warm and high-salinity seawaterintrusion such as the SCS Diluted Water…  相似文献   

UBV RI CCD photometric study of the open clusters Basel 4 and NGC 7067     

R. K. S. Yadav  Ram Sagar 《Monthly notices of the Royal Astronomical Society》2004,349(4):1481-1492

  相似文献